全钒离子氧化还原液流电池电极活性物质的研究

广东工业大学学报 ›› 2000, Vol. 17 ›› Issue (4): 78-80.

全钒离子氧化还原液流电池电极活性物质的研究

广东工业大学轻工化工学院!广东广州510090；中南工业大学化学系!湖南长沙410083；

出版日期:2000-11-16 发布日期:2000-11-16

Study on Electrode Active Materials for all Vanadium Redox Flow Battery

(1.Faculty of Chemical Engineering and Light Industry,GDUT,Guangzhou,510090,China; 2.Dept. of Chemistry,CSUT,Changsha,410083,China)

Online:2000-11-16 Published:2000-11-16

摘要/Abstract

摘要： 介绍了以VOSO4 为原料 ,电解制备全钒离子氧化还原液流电池的正极活性物质V(Ⅴ )盐和负极活性物V(Ⅱ )盐 ,并用循环伏安法研究了它们在石墨电极上的电化学性质。结果表明 ,在硫酸溶液中 ,作为全钒电池的正极和负极V(Ⅴ ) /V(Ⅳ )和V(Ⅲ ) /V(Ⅱ )电对在石墨电极上的氧化还原反应均为单电子准可逆过程

张环华；肖楚民；张平民； . 全钒离子氧化还原液流电池电极活性物质的研究[J]. 广东工业大学学报, 2000, 17(4): 78-80.

ZHANG Huan hua 1,XIAO Chu min 1,ZHANG Ping min 2 . Study on Electrode Active Materials for all Vanadium Redox Flow Battery[J]. Journal of Guangdong University of Technology, 2000, 17(4): 78-80.

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[3] M Skyllax-Kazacos,Fgrossmith.Efficient Vanadium redox flow Cell. Journal of the Electrochemical Society . 1987

[4] M Rychcik,M Skyllas-Kazacos.Characteristics of a new all-vanadium redox flow battery. Journal of Power Sources . 1988

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