广东工业大学学报 ›› 2015, Vol. 32 ›› Issue (2): 126-131.doi: 10.3969/j.issn.1007

• 综合研究 • 上一篇    下一篇

CT/PVDF超滤膜的制备与油水分离应用的研究

 区文仕, 张国庆, 袁晓娇, 苏攀   

  1. 广东工业大学 材料与能源学院,广东 广州 510006
  • 收稿日期:2014-04-08 出版日期:2015-05-30 发布日期:2015-05-30
  • 作者简介:区文仕(1990-),男,硕士研究生,主要研究方向为功能性膜材料与膜分离.
  • 基金资助:

    国家国际科技计划专项(2011DFB91560)

Production of CT/PVDF Ultrafiltration Membrane and Its Application to Oilwater Separation

Ou Wen-shi, Zhang Guo-qing, Yuan Xiao-jiao, Su Pan   

  1. School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
  • Received:2014-04-08 Online:2015-05-30 Published:2015-05-30

摘要: 以钙钛矿型粉末(CT powder)作为无机添加剂与聚偏氟乙烯(PVDF)共混,采用相转换法合成了有机-无机共混超滤膜.利用平板错流超滤装置对超滤膜进行纯水通量、油水乳化液截留以及抗污染性能测试;通过扫描电子显微镜(SEM)观察了膜的表面形貌、断面结构和污染物分布情况;通过污水实验,测试CT/PVDF超滤膜的抗污染性能及自净性能.结果表明:当添加质量分数为1% CT powder时,可以较大地提高PVDF超滤膜的通量,减缓膜通量下降率,提高其抗污染性能和自净能力.且在油水分离实验中,渗透液水质,如浊度、油含量和化学需氧量等,均达国家排放标准.

关键词: 聚偏氟乙烯; 钙钛矿型粉末(CT powder); 超滤膜; 油水分离;   抗污染性能

Abstract: The organicinorganic blended ultrafiltration membrane is synthesized by the phase transformation method, which mixed perovskite powder (CT powder) with polyvinylidene fluoride(PVDF). The pure water flux, oil rejection performance and antifouling property of ultrafiltration membrane were tested by the plate crossflow ultrafiltration device. The surface morphology, crosssectional morphology and the pollutants distribution of membrane were detected by using scanning electron microscope (SEM). The antifouling property and selfcleaning performance of CT/PVDF ultrafiltration membrane were tested by sewage experiments. The results show that adding 1% CT powder can greatly improve the flux of PVDF ultrafiltration membrane, slow down the rate of membrane flux decline and improve its antifouling property and selfpurification. In the oilwater separation experiment, the quality of penetrating fluid, such as turbidity, oil content and chemical oxygen demand are up to national emission standards.

Key words: PVDF; CT powder; ultrafiltration membrane; oilwater separation; antifouling property

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