广东工业大学学报 ›› 2018, Vol. 35 ›› Issue (04): 111-118.doi: 10.12052/gdutxb.170162

• 综合研究 • 上一篇    下一篇

碳化棉织物作为微生物燃料电池廉价阳极材料的研究

曾丽珍1,2, 何苗1   

  1. 1. 广东工业大学 物理与光电工程学院, 广东 广州 510006;
    2. 华南师范大学 分析测试中心, 广东 广州 510006
  • 收稿日期:2017-11-30 出版日期:2018-07-09 发布日期:2018-06-06
  • 通信作者: 何苗(1965–),男,教授,博士生导师,主要研究方向为LED材料.E-mail:herofategdut@126.com E-mail:herofategdut@126.com
  • 作者简介:曾丽珍(1985-),女,实验师,博士研究生,主要研究方向为微生物燃料电池电极材料.
  • 基金资助:
    广东省科技计划项目（2014B050505020，2015B010114007，2014B090904045）；广州市科技计划项目（201604016095，2016201604030027）；华南师范大学青年教师科研培育基金项目（15KJ12）

Application of Carbonized Waste Cotton Textiles as Electrode in Microbial Fuel Cells

Zeng Li-zhen1,2, He Miao1   

  1. 1. School of Physics and Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, China;
    2. Analysis and Testing Center, South China Normal University, Guangzhou 510006, China
  • Received:2017-11-30 Online:2018-07-09 Published:2018-06-06
  • Supported by:
     

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摘要： 使用廉价的日常废棉纺织物作为原材料，通过碳化处理制备了一种新颖的、生物相容性的、多孔的、高导电性的、低成本的碳化棉织物（CCTs）电极，并且用于微生物燃料电池（MFCs）的阳极材料.采用场发射扫描电子显微镜（FESEM），X射线衍射（XRD），拉曼光谱（Raman），傅里叶变换红外光谱（FTIR），X射线光电子能谱（XPS）和Brunauer-Emmett-Teller （BET）等方法进行表征.表征结果显示，CCT-1000电极的表面比较粗糙，比表面积为209.64 m2·g–1，大大增强了电极与细菌之间的相互作用，从而增加了细菌在电极上的负载量，促进了细菌胞外电子传递（EET）.使用CCT-1000阳极的MFC的输出功率为738±20 mW·m–2，比使用商业碳毡阳极的MFC的输出功率提高了43%.另外充分利用廉价的废棉纺织物，可以大大降低MFCs的成本，同时减少环境污染问题.

关键词: 碳化, 棉织物, 廉价, 微生物燃料电池, 阳极

Abstract: A new biocompatible, porous, high conductive and low-cost electrode, carbonized waste cotton textiles (CCTs) was developed as anode electrode materials for membraneless microbial fuel cells (MFCs). The CCTs are characterized by using Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectrum (FTIR), X-ray photoelectron spectroscopy (XPS) and Brunauer-Emmett-Teller (BET) method. The results show that the CCT-1000 electrode provides a low electrical resistivity (7.56 Ω·sq-1) and a large surface area (209.64 m2·g-1) for bacterial growth, hence greatly increasing the loading amount of bacterial cells and facilitating the extracellar electron transfer (EET). The MFC using the CCT-1000 anode delivers a power output of 738±20 mW·m-2, which is 43% higher than that of commercial carbon felt anode with the same configuration and non-catalyst modification. Moreover, making full use of the cheap electrode and membraneless configuration can greatly reduce cost of MFCs.

Key words: carbonization, waste cotton textiles, low-cost, microbial fuel cell, anode

中图分类号: 

  • TM911.4
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