基于能量传递可调色度ZnNb2O6:Dy3+, Eu3+荧光粉的制备及其发光性能研究

doi:10.12052/gdutxb.190024

摘要/Abstract

摘要： 采用传统的高温固相法合成了Dy³⁺/Eu³⁺单掺杂和Dy³⁺，Eu³⁺共掺的具有可调色度ZnNb₂O₆荧光粉。利用X射线衍射、激发和发射光谱、荧光寿命以及扫描电镜（SEM）等系统地分析了上述合成样品。ZnNb₂O₆在200~500 nm有着较宽的吸收带，呈现出具有自激活发光的特性。ZnNb₂O₆：0.08Dy³⁺和ZnNb₂O₆：0.08Dy³⁺，0.03Eu³⁺荧光粉的色度坐标接近标准白光（0.33，0.33）。通过Dy³⁺作为敏化剂，Eu³⁺作为红光发光来调节样品的发光颜色；通过荧光光谱以及荧光寿命衰减曲线确定Dy³⁺至Eu³⁺离子的能量传递机制。分析得出Dy³⁺离子到Eu³⁺离子的能量传递机制遵循非辐射电偶极矩-电四极矩作用。据此，本文制备的ZnNb₂O₆：0.08Dy³⁺，yEu³⁺荧光粉在紫外汞灯白光源和其他固态照明技术中具有一定的应用价值。

关键词: 荧光粉, 光致发光, X射线衍射, 能量传递

Abstract: In order to study new rare earth ion doped chromaticity phosphors, a color-tunable phosphor based on Dy³⁺/Eu³⁺ co-doped ZnNb₂O₆ were synthesized by a traditional solid-state reaction method. X-ray powder diffraction (XRD), Scanning Electron Microscope (SEM), photoluminescence spectra and decay curves were utilized to characterize the as-prepared phosphors. The ZnNb₂O₆ host was proved to be a self-activated phosphor with broad absorption range from 200 to 550 nm. The color coordinate (x, y) values of ZnNb₂O₆:0.08Dy³⁺ and ZnNb₂O₆:0.08Dy³⁺, 0.03Eu³⁺ phosphors were already very close to the standard white light (0.33, 0.33). Therefore, Dy³⁺ was selected as the sensitizer ion and red component from Eu³⁺ adjusted to control the emission color. The energy transfer from Dy³⁺ to Eu³⁺ was confirmed based on the luminescence spectra and decay curves. Furthermore, the energy transfer mechanism was deduced to be the dipole-quadrupole interaction. In general, the ZnNb₂O₆:0.08Dy³⁺, yEu³⁺ phosphors obtained may have potential application in the ultraviolet pumped white light sources and display devices etc.

Key words: phosphors, luminescence, X-ray diffraction, energy transfer

中图分类号:

TB321

梁柏鑫, 易双萍, 胡耕樵, 方志雄, 赵韦人. 基于能量传递可调色度ZnNb₂O₆:Dy³⁺, Eu³⁺荧光粉的制备及其发光性能研究[J]. 广东工业大学学报, 2020, 37(01): 34-41.

Liang Bo-xin, Yi Shuang-ping, Hu Geng-qiao, Fang Zhi-xiong, Zhao Wei-ren. Synthesis and Luminescence Properties of Multicolor Tunable ZnNb₂O₆: Dy³⁺, Eu³⁺ Phosphors Based on Energy Transfer[J]. Journal of Guangdong University of Technology, 2020, 37(01): 34-41.

参考文献

[1] WU C, LI Y, GONG H, et al. Niobium-oxygen octahedra and oxygen interstitial defect emissions in calcium niobate matrix and its color manipulation via doping Pr³⁺[J]. AIP Advances, 2017, 7(2):1-6
[2] WAN L, XIONG F Q, LI Y, et al. Low defect density, high surface area LaNbON₂ prepared via nitridation of La₃NbO₇[J]. Materials Letters, 2017, 188:212-214
[3] WANG T, HU Y, CHEN L, et al. A White-Light emitting phosphor LuNbO₄:Dy³⁺ with tunable emission color manipulated by energy transfer from NbO₄^3- groups to Dy³⁺[J]. Journal of Luminescence, 2017, 181:189-195
[4] MO F, ZHOU L, PANG Q, et al. Synthesis and luminescent properties of Zn_0.890Nb₂O₆:Eu^0.053+, Bi^0.0053+, M^0.055+(M=Li, Na, K) phosphors[J]. Current Applied Physics, 2013, 13(2):331-335
[5] VERMA T, AGRAWAL S. Photoluminescent and Thermoluminescent Studies of Dy³⁺ and Eu³⁺ Doped Y₂O₃ phosphors[J]. J Fluoresc, 2018, 28(1):453-464
[6] LI Y, XIONG F Q, OU R, et al. Chloride flux growth of crystalline strontium niobates and nitridation to perovskite SrNbO₂N[J]. Ceramics International, 2017, 43(10):7695-7700
[7] LIU X, LIN C, LUO Y, et al. Host-sensitized luminescence of Dy³⁺, Pr³⁺, Tb³⁺ in polycrystalline SrIn₂O₄ for field emission displays[J]. Journal of The Electrochemical Society, 2007, 154(1):J21-27
[8] 张璐, 易双萍, 赵韦人, 等. 紫外激发GdNbO₄:Tb³⁺色度可调荧光粉的制备和发光性能的研究[J]. 广东工业大学学报, 2017, 34(5):91-95
ZHANG L, YI S P, ZHAO W R, et al. Synthesis and photoluminescence properties of multicolor tunable GdNbO₄:Tb³⁺ phosphors[J]. Journal of Guangdong University of Technology, 2017, 34(5):91-95
[9] YANG M, ZHAO X, JI Y, et al. Hydrothermal approach and luminescent properties for the synthesis of orthoniobates GdNbO₄:Ln³⁺(Ln=Dy, Eu) single crystals under high-temperature high-pressure conditions[J]. New J Chem, 2014, 38(9):4249-4257
[10] MAHESH S K, RAO P P, FRANCIS T L, et al. Intense red line emitting phosphor LuNbO₄:Eu³⁺ for white-light emitting diode applications[J]. Materials Letters, 2014, 120:115-117
[11] LI K, LIU X, ZHANG Y, et al. Host-sensitized luminescence properties in CaNb₂O₆:Ln³⁺(Ln³⁺=Eu³⁺/Tb³⁺/Dy³⁺/Sm³⁺) phosphors with abundant colors[J]. Inorg Chem, 2015, 54(1):323-333
[12] XU D, LIU Y, ZHOU Q, et al. Optical phonon behaviors of columbite ZnNb₂O₆ single crystal[J]. Journal of Alloys and Compounds, 2015, 618:694-699
[13] JIANG C, BRIK M G, LI L, et al. The electronic and optical properties of a narrow-band red-emitting nanophosphor K₂NaGaF₆:Mn⁴⁺ for warm white light-emitting diodes[J]. Journal of Materials Chemistry C, 2018, 6(12):3016-3025
[14] WANG R, ZHANG W, XU Y, et al. Upconversion emissions in ZnNb₂O₆:Ho³⁺/Yb³⁺ ceramics[J]. Optics & Laser Technology, 2014, 58:52-55
[15] GOU J, WANG Y, GUO H. Energy transfer in Dy³⁺ and Al³⁺ co-doping ZnNb₂O₆[J]. Journal of Physics:Conference Series, 2009, 152(1):012081
[16] GAO S P, QIAN Y N, WANG B. Photoluminescence of rare-earth ion (Eu³⁺, Tm³⁺, and Er³⁺)-doped and co-doped ZnNb₂O₆ for solar cells[J]. Chinese Physics B, 2015, 24(8):1-6
[17] ZHOU Y Y, Qiu Z F, LU M K, et al. Photoluminescence Characteristics of pure and Dy-doped ZnNb₂O₆ nanoparticles prepared by a combustion method[J]. The Journal of Physical Chemistry C, 2007, 111(28):10190-10193
[18] PULLAR R C. The synthesis, properties, and applications of columbite niobates (M²⁺Nb₂O₆):a critical review[J]. Journal of the American Ceramic Society, 2009, 92(3):563-577
[19] FANG T H, HSIAO Y J, CHANG Y S, et al. Photoluminescent characterization of KNbO₃:Eu³⁺[J]. Materials Chemistry and Physics, 2006, 100(2-3):418-422
[20] WANG Y, ENDO T, XIE E, et al. Luminescence properties of Ca₄GdO(BO₃)₃:Eu³⁺ in ultraviolet and vacuum ultraviolet regions[J]. Microelectronics Journal, 2004, 35(4):357-361
[21] XIAN J, YI S, DENG Y, et al. Synthesis and photoluminescence properties of Ln³⁺(Ln³⁺=Tb³⁺, Dy³⁺, Sm³⁺, Er³⁺)-doped Ca₂Nb₂O₇ phosphors[J]. Physica B:Condensed Matter, 2016, 483:19-25
[22] LIU C, ZHOU W, SHI R, et al. Host-sensitized luminescence of Dy³⁺ in LuNbO₄ under ultraviolet light and low-voltage electron beam excitation:energy transfer and white emission[J]. Journal of Materials Chemistry C, 2017, 5(35):9012-9020
[23] 黄军, 易双萍, 冼洁强, 等. Eu³⁺和Dy³⁺ 共掺单基质Ba₂CaWO₆白色荧光粉的合成与发光性质[J]. 广东工业大学学报, 2016, 33(2):76-80
HUANG J, YI S P, XIAN J Q, et al. Synthesis and luminescent properties of Eu³⁺ and Dy³⁺ co-doped single host Ba₂CaWO₆ white phosphors[J]. Journal of Guangdong University of Technology, 2016, 33(2):76-80
[24] SHI X, WANG Z, TAKEI T, et al. Selective crystallization of four tungstates (La₂W₃O₁₂, La₂W₂O₉, La₁₄W₈O₄₅, and La₆W₂O₁₅) via hydrothermal reaction and comparative study of Eu³⁺ luminescence[J]. Inorg Chem, 2018, 57(11):6632-6640
[25] FU A, GUAN A, YU D, et al. Synthesis, structure, and luminescence properties of a novel double-perovskite Sr₂LaNbO₆:Mn⁴⁺ phosphor[J]. Materials Research Bulletin, 2017, 88:258-265
[26] JHA K, VISHWAKARMA A K, JAYASIMHADRI M, et al. Multicolor and white light emitting Tb³⁺/Sm³⁺ co-doped zinc phosphate barium titanate glasses via energy transfer for optoelectronic device applications[J]. Journal of Alloys and Compounds, 2017, 719:116-124
[27] SUN J, ZENG J, SUN Y, et al. Tunable luminescence of Ce³⁺/Mn²⁺-coactivated Sr₃Gd(PO₄)₃ with efficient energy transfer for white-light-emitting Diode[J]. Journal of Luminescence, 2013, 138:72-76
[28] ZHANG X, ZHANG J, CHEN Y. Broadband-excited and efficient blue/green/red-emitting Ba₂Y₅B₅O₁₇:Ce³⁺, Tb³⁺, Eu³⁺ phosphors using Tb³⁺-bridged Ce³⁺-Eu³⁺ energy transfer[J]. Dyes and Pigments, 2018, 149:696-706
[29] SUN J, ZENG J, SUN Y, et al. Photoluminescence properties and energy transfer of Ce³⁺, Eu²⁺ co-doped Sr₃Gd(PO₄)₃ phosphor[J]. Journal of Alloys and Compounds, 2012, 540:81-84
[30] WANG H, ZHOU X, YAN J, et al. (Ln³⁺=Eu³⁺/Dy³⁺/Dy³⁺, Eu³⁺) doped NaGd(MoO₄)₂ phosphors with uniform morphologies:hydrothermal synthesis, luminescent properties, energy transfer and color tunable emission[J]. Journal of Luminescence, 2018, 195:170-175

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基于能量传递可调色度ZnNb₂O₆:Dy³⁺, Eu³⁺荧光粉的制备及其发光性能研究

Synthesis and Luminescence Properties of Multicolor Tunable ZnNb₂O₆: Dy³⁺, Eu³⁺ Phosphors Based on Energy Transfer

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