广东工业大学学报 ›› 2022, Vol. 39 ›› Issue (04): 113-120.doi: 10.12052/gdutxb.210058

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金属有机框架/铋基复合材料的光催化技术应用研究进展

曹怡婷1, 王俏1,2, 许泽涛1, 吕冠衡1   

  1. 1. 广东工业大学 土木与交通工程学院, 广东 广州 510006;
    2. 哈尔滨工业大学 城市水资源与水环境国家重点实验室, 黑龙江 哈尔滨 150090
  • 收稿日期:2021-04-12 出版日期:2022-07-10 发布日期:2022-06-29
  • 通信作者: 王俏(1991–)，女，特聘副教授，博士，主要研究方向为水污染处理技术，E-mail：wangqiao@gdut.edu.cn
  • 作者简介:曹怡婷(1998–)，女，硕士研究生，主要研究方向为水污染处理技术
  • 基金资助:
    国家自然科学基金青年基金资助项目(22006200)；城市水资源与水环境国家重点实验室开放项目(HC202154)；广东工业大学青年百人A启动项目(220413320)

Research Progress of MOF/Bismuth-based Semiconductor Composites in Photocatalytic Technology

Cao Yi-ting1, Wang Qiao1,2, Xu Ze-tao1, Lyu Guan-heng1   

  1. 1. School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, China;
    2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China
  • Received:2021-04-12 Online:2022-07-10 Published:2022-06-29

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摘要： 光催化技术在环境修复和能源转换方面极具潜力，其核心为高效光催化剂的设计和开发。铋基半导体和金属有机框架(Metal-organic Frameworks，MOFs)材料耦合形成的复合材料具有优异的光催化活性，逐渐成为备受研究人员关注的一类热点材料。本文重点介绍了MOF/铋基半导体复合材料(MOF/Bismuth-based Semiconductor Composites，MBCs)的制备方法；继而论述了MBCs在有机污染物降解、Cr(VI)还原、光解水、合成氨等方面的应用。最后，指出了现阶段MBCs光催化中存在的问题，并展望了未来MBCs光催化技术领域的发展方向。

关键词: 金属有机框架, 铋基半导体, 光催化, 环境修复, 能源转换

Abstract: Photocatalysis has been regarded as an efficient technology in environmental remediation and energy conversion, and its core is the design and development of efficient photocatalysts. The composites of the bismuth-based semiconductors combined with metal-organic frameworks (MOFs) have attracted much attention due to their high photocatalytic activity. A review is conducted on recent advances in MOF/bismuth-based semiconductor composites (abbreviated as MBCs). On this basis, the synthesis methods of MBCs are described in detail, and then the applications of MBCs in organic pollutant degradation, Cr(VI) reduction, water (H2O) splitting, nitrogen (N2) fixation discussed. Finally, the unsolved problems of MBCs are discussed and the future development prospects proposed.

Key words: metal-organic frameworks, bismuth-based semiconductor, photocatalysis, environmental remediation, energy conversion

中图分类号: 

  • O643.3
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