广东工业大学学报

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木质素磺酸钠诱导调控FeNi催化剂结构与OER性能研究

钟晓文1, 卫政涛1, 陈达朗1, 黄勇宏1, 王晓菲1,2, 林绪亮1,2,3   

  1. 1. 广东工业大学 轻工化工学院, 广东 广州, 510006;
    2. 化学与精细化工广东省实验室 揭阳分中心, 广东 揭阳, 515200;
    3. 广东工业大学 广东省植物资源生物炼制重点实验室, 广东 广州, 510006
  • 收稿日期:2024-05-13 出版日期:2024-10-08 发布日期:2024-11-22
  • 通信作者: 王晓菲(1991–)，女，博士，助理研究员，主要研究方向为木质素高效催化转化，E-mail：wxfeifei@gdut.edu.cn;林绪亮(1988–)，男，博士，教授，主要研究方向为木质素碳基功能材料及其应用，E-mail：xllin@gdut.edu.cn E-mail:wxfeifei@gdut.edu.cn;xllin@gdut.edu.cn
  • 作者简介:钟晓文(1997–)，女，硕士研究生，主要研究方向为木质素碳基功能材料及其应用，E-mail：251214530@qq.com
  • 基金资助:
    国家自然科学基金资助项目(22178069)

Study on the Regulation of FeNi Catalysts Structure and OER Performance Induced by Lignosulfonate

Zhong Xiao-wen1, Wei Zheng-tao1, Chen Da-lang1, Huang Yong-hong1, Wang Xiao-fei1,2, Lin Xu-liang1,2,3   

  1. 1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;
    2. Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Jieyang 515200, China;
    3. Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangdong University of Technology, Guangzhou 510006, China
  • Received:2024-05-13 Online:2024-10-08 Published:2024-11-22

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摘要： 电解水制氢具有良好的应用前景，但其阳极析氧反应(Oxygen Evolution Reaction, OER)由于四电子耦合转移机制而具有更大的能垒和更缓慢的动力学，成为电解水的限速反应。因此，研发高效、稳定的OER电催化剂已成为当前电解水产业的迫切需求。本文通过水热自组装和高温炭化热解制备了硫掺杂木质素衍生碳包覆非贵金属铁镍催化剂(FeNi@SC)。FeNi@SC在碱性介质中表现出卓越的OER活性和长期稳定性。在电流密度为10 mA·cm–2时具有216 mV的低过电位，远低于商业贵金属催化剂Ru/C (320 mV) ，并具有长达100 h的优异稳定性。实验结果表明，FeNi双金属协同作用以及S对碳载体的缺陷掺杂，优化了中间体的吸附过程，促进了OER性能。此外，由于木质素骨架与金属离子之间的强配位作用，制备得到的碳包覆层有效地防止了FeNi金属在反应过程中的浸出和团聚。该研究为开发具有高活性和稳定性的OER电催化剂提供了一种有前景的方法，同时也为木质素的高值化利用提供了思路。

关键词: 木质素, 析氧反应, 铁镍, 电催化

Abstract: Hydrogen production via water electrolysis holds promising application prospects. However, the oxygen evolution reaction (OER) at the anode encounters a higher energy barrier and sluggish kinetics due to its four-electron coupling transfer mechanism. This makes OER as the rate-limiting step in water electrolysis. Consequently, the development of efficient and stable OER electrocatalysts has become an urgent need. In this study, a sulfur-doped lignin-derived carbon-encapsulated iron-nickel catalyst (FeNi@SC) was prepared through hydrothermal self-assembly and high-temperature carbonization pyrolysis. This non-precious metal catalyst exhibited exceptional OER activity and long-term stability in alkaline media. Specifically, FeNi@SC achieved a low overpotential of 216 mV at a current density of 10 mA·cm–2, significantly lower than the commercial precious metal catalyst Ru/C (320 mV) , and demonstrated remarkable stability over 100 h. Experimental results reveal that the synergistic effect of FeNi bimetal and sulfur doping promotes the OER process. Moreover, the strong coordination between the lignin framework and metal ions, coupled with the protective carbon coating, effectively prevents the leaching and agglomeration of FeNi alloy during the reaction. Our findings may provide a promising approach for developing highly active and stable OER catalysts, and also offer a strategy for the valorization of lignin.

Key words: lignin, oxygen evolution reaction, iron-nickel, electrocatalysis

中图分类号: 

  • TQ151
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