Journal of Guangdong University of Technology ›› 2024, Vol. 41 ›› Issue (05): 66-71.doi: 10.12052/gdutxb.230197

• Environmental Science & Engineering • Previous Articles     Next Articles

Determination of Volatile Sulfur Compounds in Livestock Waste Compost by Gas Chromatography-ion Mobility Spectrometry

Duan Teng-fei1, Zuo Lin-zi2, Zhang Li-xin3, Xu Yan-bin1   

  1. 1. School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China;
    2. Analysis and Test Center, Guangdong University of Technology, Guangzhou 510006, China;
    3. Shandong Haineng Scientific Instrument Co. Ltd., Dezhou 251500, China
  • Received:2023-12-06 Online:2024-09-25 Published:2024-10-08

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Abstract: A method for determination of volatile sulfur compounds-dimethyl sulfide, diethyl sulfide, dimethyl disulfide, and carbon disulfide in livestock waste compost was established using gas chromatography–ion mobility spectroscopy technology. The sample was collected using a gas sampling bag after ammonia removal, separated on a packed gas chromatography column of MXT-1, and detected in both positive and negative modes under the optimized experimental conditions. The results showed that the four sulfur compounds represented good linearity (R2>0.99) in their respective linear ranges; the detection limits were 0.008~0.097 mg/m3 with recoveries of 85%~116% and relative standard deviation (RSD) of 1.13%~8.42%. The method is free of pretreatment such as pre-concentration or enrichment, sensitive and rapid, and the collection of odorous composting gas can be conducted using a gas sampling bag. The method is sensitive and rapid, which can be used for on-site monitoring of volatile sulfur in compost gas.

Key words: gas chromatography-ion mobility spectrometry, detection, volatile sulfur compounds

CLC Number: 

  • X831
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