镓离子掺杂的CsPbBr3量子点的制备及其性能研究

    Preparation and Properties of CsPbBr3 Quantum Dots Doped with Gallium Ions

    • 摘要: 通过改进的一锅热注入法, 研究了不同Ga3+的量掺杂CsPbBr3后的荧光光谱变化, 并且高荧光量子产率(Photoluminescence Quantum Yield,PLQY)在Ga3+和Pb2+的进料摩尔比为1∶1的时候达到最高, 是47%的蓝光。本文成功地将掺杂Ga3+的钙钛矿量子点负载到了硼酸钴晶体材料上, 发现其荧光强度在很长一段时间都没有明显的猝灭现象, 这增强了钙钛矿量子的稳定性。

       

      Abstract: We studied the fluorescence spectrum changes after doping CsPbBr3 with different amounts of Ga3+ by an improved one-pot hot-injection method, and photoluminescence quantum yield (PLQY) reached the highest when the molar ratio of Ga3+ and Pb2+ was 1∶1, which was 47% blue light. We successfully loaded Ga3+-doped perovskite quantum dots onto the cobalt borate crystal material, and found that the fluorescence intensity has no obvious quenching phenomenon for a long time, which enhances the stability of the perovskite quantum.

       

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