Journal of Guangdong University of Technology ›› 2017, Vol. 34 ›› Issue (02): 17-22.doi: 10.12052/gdutxb.160163

Previous Articles     Next Articles

Synthesis and Washing-Assistant Properties of Poly (disodium cis-epoxysuccinate) Detergent Builder

Guo Jian-wei, Wen Wei-qiu, Chen Shao-hua, Yue Hang-bo   

  1. School of Chemical Engineering & Light Industry, Guangdong University of Technology, Guangzhou 510006, China
  • Received:2016-11-23 Online:2017-03-09 Published:2017-03-09

Abstract:

Poly (disodium cis-epoxysuccinate) PESA as a non-nitrogen and non-phosphors biodegradable polymer showing good chelating ability to calcium and magnesium ions and good buffer capacity can be used in detergent industry. PESA Polymers were synthesized by solution polymerization of disodium cis-epoxysuccinate in the presence of calcium hydroxide as initiator, while disodium cis-epoxysuccinate obtained by epoxidation of maleic anhydride using sodium tungstate as catalyst and hydrogen peroxide as oxidation. The molecule structures of both materials were characterized by IR and 1H NMR. The detergent properties of PESA polymers were investigated. The optimum synthetic conditions were found:reaction temperature=90℃, reaction time=6 h, mass content of Ca(OH)2=4%. And the calcium chelating and dispersing abilities (Expressed as CaCO3) were quantified as 367.5 mg CaCO3/g and 112.8 mg CaCO3/g, respectively.

Key words: disodium cis-epoxysuccinate, non-phosphorus detergent polymer, solution polymerization

CLC Number: 

  • TQ317.4

[1] 刘有才.洗涤剂中磷酸盐的应用现状与趋势[J].日用化学品科学, 1996, 6(11):10-13.LIU Y C. Application status and trend of phosphate detergent[J]. Detergent and Cosmetics, 1996, 6(11):10-13.
[2] 阿部芳郎.洗涤剂通论[M].张金廷, 张锦德译.北京:中国轻工业出版社, 1992.
[3] 王美杰.水体富营养化的危害及防治措施[J]. 科技信息, 2012(10):60.WANG M J. The harm and prevention measures of eutrophication[J]. Science & Technology Information, 2012(10):60.
[4] 王倩.微生物在治理水体污染中的作用[J].中国科技博览, 2011(36):335.WANG Q. The role of microorganisms in water pollution treatment[J]. China Science and Technology Review, 2011(36):335.
[5] FORSBERG C. Which policies can stop large scale eutrophication[J]. Water Science and Technol, 1998, 37(3):193-200.
[6] 许智芳, 史海生, 王科. 代磷洗涤助剂的性能及应用前景[J]. 中国洗涤用品工业, 2011(1):64-68.XU Z F, SHI H S, WANG K. The performance of the generation of phosphorus detergent auxiliary and application prospects[J]. China Cleaning Industry, 2011(1):64-68.
[7] 罗灯洪, 郑庆康, 黄志斌, 等. 马来酸酐-丙烯酸共聚物结构与皂洗性能的关系[J]. 针织工业, 2010(10):29-32.LUO D H, ZHENG Q K, HUANG Z B, et al. The relationship between the structure of maleic anhydride-acrylic acid copolymer and the property of soap washing[J]. Knitting Industries, 2010(10):29-32.
[8] 李雄, 郭建维, 潘莉辉, 等.低分子马来酸酐-牛磺酸共聚物的合成及应用性能研究[J].广东工业大学学报, 2015, 32(9):30-34.LI X, GUO J W, PAN L H, et al. Synthesis and application performance of maleic anhydride-taurine oligomer[J]. Journal of Guangdong University of Technology, 2015, 32(9):30-34.
[9] 王寿武, 邓应淼, 周雪婷, 等. 聚丙烯酸钠的合成及性能研究[J]. 精细石油化工进展, 2010(5):42-43.WANG S W, DENG Y M, ZHOU X T, et al. Synthesis and properties of sodium polyacrylate[J]. Advances in Fine Petrochemicals, 2010(5):42-43.
[10] 郭建维, 马倩, 崔亦华, 等.用于无磷洗涤助剂的可生物降解共聚物P(AA-co-MDO)的合成及表征[J].高分子学报, 2012(9):958-964.GUO J W, MA Q, CUI Y H, et al. Synthesis and characterization of biodegradable copolymers as non-phosphorous detergent builders[J]. Acta Polymerica Sinica, 2012(9):958-964.
[11] 傅淑琴, 郭建维, 马倩, 等.可生物降解高分子助洗剂P(AA-co-MDO)的制备与性能[J].广东工业大学学报, 2013, 30(4):39-42.FU S Q, GUO J W, MA Q, et al. Preparation and properties of biodegradable polymer detergent builder[J]. Journal of Guangdong University of Technology, 2013, 30(4):39-42.
[12] PAN L H, GUO J W, ZHU D Y. Synthesis of poly (maleic anhydride-co-taurine) as a biodegradable detergent builder[J]. Journal of Surfactants and Detergents. 2014, 17(5):865-869.
[13] 陈磊, 孔秀琴, 周昌琴, 等.环保型阻垢剂PESA的相关研究[J]. 应用化工, 2016, 45(10):1824-1827.CHEN L, KONG X Q, ZHOU C Q, et al.Related study on environmental protection type scale inhibitor PESA[J]. Applied Chemical Industry, 2016, 45(10):1824-1827.
[14] 高美玲, 李海花, 张利辉, 等. 聚环氧琥珀酸的改性及其阻垢分散性能研究[J]. 现代化工, 2016, 36(9):67-71 GAO M L, LI H H, ZHANG L H, et al. Influence of modified polyaspartic acid on scale inhibition and dispersion capacities[J]. Modern Chemical Industry, 2016, 36(9):67-71.
[15] 全国染料标准化技术委员会.纺织印染助剂螯合剂螯合能力的测定:GB/T 21884-2008[S].北京:中国标准出版社, 2008.
[16] 陈静. 马来酸酐-丙烯酸共聚物钠盐的合成及性能研究[J]. 精细石油化工, 2001, 5(3):13-15.CHEN J.Synthesis of maleic anhydride-acrylic acid copolymer and its properties[J].Speciality Petrochemicals, 2001, 5(3):13-15.

[1] LI Ming-qing,ZHOU Chang-ren. Preparation of Pressure-sensitive Adhesive Used for Polyethylene Film [J]. Journal of Guangdong University of Technology, 2005, 22(2): 6-11.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!