Journal of Guangdong University of Technology ›› 2022, Vol. 39 ›› Issue (04): 107-112.doi: 10.12052/gdutxb.210117

Previous Articles     Next Articles

In2Se3 Sheets as Photosensitizers to Enhance the Photocatalytic Performance of Graphene Oxide/WS2/Mg-doped ZnO Composite under Natural Sunlight

Long Hui1, Wei Zi-qiao1, Luo Si-yao2, Dong Hua-feng1, Chen Chuan-sheng2   

  1. 1. School of Physics and Optoelectronic Engineering, Guangdong University of technology, Guangzhou 510006, China;
    2. College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha 410114, China
  • Received:2021-08-04 Online:2022-07-10 Published:2022-06-29

Abstract: With the development of photocatalytic technology, the research and exploration of photocatalytic properties of 2D materials have also attracted much attention. The photocatalytic performance of graphene oxide/WS2/Mg-doped ZnO (rGOWMZ) composites under 600 ℃ annealing is excellent because the degradation rate of Rhodamine B (RhB) is 99.6% under natural light, with the added 0.5% amount of In2Se3 sheets which is a direct bandgap semiconductor. The In2Se3 sheets prepared through liquid exfoliation are about 100 nm and ~5 atomic layers thickness. The composites are carried out with Transmission electron microscope (TEM), Atomic force microscope (AFM), X-ray diffraction (XRD), and Scanning electron microscope (SEM). And the rGOWMZ+In2Se3 composites exhibit excellent photocatalytic property, showing great potential in photocatalyst application.

Key words: In2Se3 sheets, 2D materials, natural sunlight, photocatalytic enhancement

CLC Number: 

  • O611.2
[1] NOVOSELOV K S, GEIM A K, MOROZOV S V, et al. Electric field effect in atomically thin carbon films [J]. Science, 2004, 306(5696): 666-669.
[2] GEIM A K, NOVOSELOV K S. The rise of graphene [J]. Nature Materials, 2007, 6(3): 183-191.
[3] MAS-BALLESTÉ R, GÓMEZ-NAVARRO C, GÓMEZ-HERRERO J, et al. 2D materials: to graphene and beyond [J]. Nanoscale, 2011, 3(1): 20-30.
[4] JOEL D C, MARINI A, JAVIER GARCÍA DE ABAJO F. Plasmon-assisted high-harmonic generation in graphene[J]. Nature Communications, 2017, 8(1): 14380.
[5] XIA F N, WANG H, JIA Y C. Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics[J]. Nature Communications, 2014, 5(1): 4458.
[6] WANG Q H, KALANTAR-ZADEH K, KIS A, et al. Electronics and optoelectronics of two-dimensional transition metal dichalcogenides [J]. Nature Nanotechnology, 2012, 7(11): 699-712.
[7] TORRES-TORRES C, PEREA-LÓPEZ N, ELÍAS A L, et al. Third order nonlinear optical response exhibited by mono- and few-layers of WS2 [J]. 2D Materials, 2016, 3(2): 021005.
[8] WANG Z W, ZHAO R W, HE J L, et al. Multi-layered black phosphorus as saturable absorber for pulsed Cr: ZnSe laser at 2.4 μm [J]. Optics Express, 2016, 24(2): 1598-1603.
[9] BONACCORSO F, COLOMBO L, YU G H, et al. Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage [J]. Science, 2015, 347(6271): 1246501.
[10] CHEN Y, TAN C L, ZHANG H, et al. Two-dimensional graphene analogues for biomedical Applications [J]. The Royal Society of Chemistry, 2015, 44(9): 2681-2701.
[11] CHENG L, LIU J J, GU X, et al. PEGylated WS2 nanosheets as a multifunctional theranostic agent for in vivo dual-modal CT/photoacoustic imaging guided photothermal therapy [J]. Advanced Materials, 2014, 26(12): 1886-1893.
[12] CHEN Y, YE D L, WU M Y, et al. Break-up of two-dimensional MnO2 nanosheets promotes ultrasensitive pH-triggered theranostics of cancer [J]. Advanced Materials, 2014, 26(41): 7019-7026.
[13] DI J, XIONG J, LI H M, et al. Ultrathin 2D photocatalysts: electronic-structure tailoring, hybridization, and applications [J]. Advanced Materials, 2018, 30(1): 1704548.
[14] LONG H, LIU S X, WEN Q, et al. In2Se3 nanosheets with broadband saturable absorption used for near-infrared femtosecond laser mode locking [J]. Nanotechnology, 2019, 30(46): 465704.
[15] VELICKY M, TOTH P S. From two-dimensional materials to their heterostructures: an electrochemist’s perspective [J]. Applied Materials Today, 2017, 8(1): 68-103.
[16] LIU X, CHEN C. Mxene enhanced the photocatalytic activity of ZnO nanorods under visible light[J]. Materials Letters, 2020, 261: 127127
[17] CHEN C S, MEI W, WANG C, et al. Synthesis of a flower-like SnO/ZnO nanostructure with high catalytic activity and stability under natural sunlight[J]. Journal of Alloys and Compounds, 2020, 826: 154122
[18] LIU X Y, LIU Q C, CHEN C S. Ultrasonic oscillation synthesized ZnS nanoparticles/layered MXene sheet with outstanding photocatalytic activity under visible light[J]. Vacuum, 2021, 183: 109834
[19] TAO X, GU Y. Crystalline-crystalline phase transformation in two-dimensional In2Se3 thin layers [J]. Nano Letters, 2013, 13(8): 3501-3505.
[20] RASMUSSEN A M, TEKLEMICHAEL S T, ELHAM M, et al. Pressure-induced phase transformation of In2Se3 [J]. Applied. Physics Letters, 2013, 102(6): 062105.
[21] JACOBS-GEDRIM R B, SHANMUGAM M, JAIN N, et al. Extraordinary photoresponse in two-dimensional In2Se3 nanosheets [J]. ACS Nano, 2013, 8(1): 514-521.
[22] POPOVIC S, TONEJC A, GRETA-PLENKOVIE B, et al. Revised and new crystal data for indium selenides [J]. Journal of Applied Crystallography, 1979, 12(4): 416-420.
[23] RADISAVLJEVIC B, Whitwick M B, KIS A. Integrated circuits and logic operations based on single-layer MoS2 [J]. Nature Nanotechnology, 2011, 5(12): 9934-9938.
[24] EDA G, FANCHINI G, HHOWALLA M. Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J]. Nature Nanotechnology, 2008, 3(5): 270-274.
[25] QUEREDA J, BIELE R, RUBIO-BOLLINGER G, et al. Strong quantum confinement effect in the optical properties of ultrathin α-In2Se3 [J]. Advanced Optical Materials, 2016, 4(12): 1939-1959.
[26] DING W J, ZHU J B, WANG Z, et al. Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other III2-VI3 van der Waals materials [J]. Nature Communications, 2017, 8(1): 14956.
[27] CHEN C S, YU W W, LIU T G, et al. Graphene oxide/WS2/Mg-doped ZnO nanocomposites for solar-light catalytic and anti-bacterial applications[J]. Solar Energy Materials & Solar Cells, 2017, 160: 43-53.
No related articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!