Journal of Guangdong University of Technology ›› 2024, Vol. 41 ›› Issue (03): 29-35.doi: 10.12052/gdutxb.230116

• Materials Science and Technology • Previous Articles     Next Articles

Synthesis and Electrochemical Research of Sodium Storage Anode SnSe2@C

Zhong Jia-rui, Lin Lin, Zheng Cheng   

  1. School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
  • Received:2023-08-28 Online:2024-05-25 Published:2024-06-14

Abstract: Tin selenide (SnSe2) is a very promising negative electrode material for sodium ion batteries, which has advantages such as high theoretical specific capacity, wide range of raw materials, and low cost. However, it is also limited by the structural damage caused by volume expansion during charging and discharging processes. A research is conducted on the successful synthesis of carbon coated tin selenide (SnSe2@C) through high-temperature annealing. Carbon coating improves the conductivity and stability of the material as sodium-ion battery anode, making SnSe2@C has high specific capacity (549.0 mAh·g-1 at 1.0 A·g-1) and excellent rate performance (427.7 mAh·g-1 at 5.0 A·g-1).

Key words: SnSe2, nano material, sodium-ion batteries, anode, electrochemistry

CLC Number: 

  • TM912.5
[1] ANIL S, ANDY A M, MYO M H, et al. Evolution of energy mix in emerging countries: modern renewable energy, traditional renewable energy, and non-renewable energy [J]. Renewable Energy, 2022, 199: 419-432.
[2] 李新喜, 袁晓娇, 张国庆, 等. 锂离子电池硅/石墨复合负极材料的制备及性能研究[J]. 广东工业大学学报, 2014, 31(2): 27-31.
LI X X, YUAN X J, ZHANG G Q, et al. Preparation and properties of silicon/graphite composites as anode materials for lithium batteries [J]. Journal of Guangdong University of Technology, 2014, 31(2): 27-31.
[3] 李越珠, 黄兴文, 廖松义, 等. 锂离子电池高镍三元正极材料LiNi0.8Co0.1Mn0.1O2研究进展[J]. 广东工业大学学报, 2021, 38(5): 68-74.
LI Y Z, HUANG X W, LIAO S Y, et al. Research progress of high nickel ternary cathode material LiNi0.8Co0.1Mn0.1O2 for lithium-ion batteries [J]. Journal of Guangdong University of Technology, 2021, 38(5): 68-74.
[4] HAGIWARA R, MATSUMOTO K, HWANG J, et al. Sodium ion batteries using ionic liquids as electrolytes [J]. Chemical Record, 2018, 19: 758-770.
[5] CHAWLA N, SAFA M. Sodium batteries: a review on sodium-sulfur and sodium-air batteries [J]. Electronics, 2019, 8(10): 1201.
[6] YANG X, ROGACH A L. Anodes and sodium-free cathodes in sodium ion batteries [J]. Advanced Energy Materials, 2020(22): 10.
[7] ZENG J J, WANG T, GU X R, et al. Nickel-templated carbon foam anodes for sodium-ion batteries [J]. Flat Chem, 2023, 40: 100508.
[8] AN B, MA Y, ZHANG G, et al. Controlled synthesis of few-layer SnSe2 by chemical vapor deposition [J]. RSC Advances, 2020, 10: 42157-42163.
[9] LIU Y, XU Y, HAN Y, et al. Facile synthesis of SnSe2 nanoparticles supported on graphite nanosheets for improved sodium storage and hydrogen evolution [J]. Journal of Power Sources, 2019, 436: 226860.
[10] 王昱官, 王伟. 二硒化锡纳米片的制备及其储钠行为研究[J]. 低碳化学与化工, 2023, 48(6) : 1-7.
WANG Y G, WANG W. Study on preparation of tindiselenide nanosheets and their sodium storage behaviors [J]. Low-Carbon Chemistry and Chemical Engineering, 2023, 48(6) : 1-7.
[11] ZHANG F, XIA C, ZHU J, et al. SnSe2 2D anodes for advanced sodium ion batteries [J]. Advanced Energy Materials, 2016, 6: 1601188.
[12] CHEN H, MU Z J, XIA Z H, et al. SnSe2 nanocrystals coupled with hierarchical porous carbon microspheres for long-life sodium ion battery anode [J]. Science China Materials, 2019, 63(4): 483-491.
[13] SHAJI N, SANTHOSHKUMAR P, KANG H S, et al. Tin selenide/N-doped carbon composite as a conversion and alloying type anode for sodium-ion batteries [J]. Journal of Alloys and Compounds, 2020, 834: 154304.
[14] XI G, JIAO X, HU X. N-doped carbon-confined SnSe2 nanoparticles as high-performance anode for lithium ion batteries [J]. Ionics, 2023, 29: 119-128.
[15] YAO W, CAI C, XIANG J, et al. SnSe2 encapsuled in N-doped carbon nanofibers as self-supporting anode for lithium-ion storage [J]. Journal of Electronic Materials, 2022, 51(12): 6654-6662.
[16] BAI J, WU H, WANG S, et al. Synthesis of CoSe2-SnSe2 nanocube-coated nitrogen-doped carbon(NC) as anode for lithium and sodium ion batteries [J]. Applied Surface Science, 2019, 488: 512-521.
[17] WU X, YANG Z, XU L, et al. SnSe2 Consecutive hybrid mechanism boosting Na+ storage performance of dual-confined SnSe2 in N, Se-doping double-walled hollow carbon spheres [J]. Journal of Energy Chemistry, 2022, 74: 8-17.
[1] Tang Fang, Xia Rong-qing, Rui Xian-hong. Al2O3 In-situ Modified Al Current Collectors for Uniform Na Plating/Stripping [J]. Journal of Guangdong University of Technology, 2023, 40(06): 88-94.doi: 10.12052/gdutxb.230116
[2] Zeng Li-zhen, He Miao. Application of Carbonized Waste Cotton Textiles as Electrode in Microbial Fuel Cells [J]. Journal of Guangdong University of Technology, 2018, 35(04): 111-118.doi: 10.12052/gdutxb.230116
[3] Li Xinxi, Yuan Xiaojiao, Zhang Guoqing, Zhang Xinhe, Zhang Lei. Preparation and Properties of Silicon/Graphite Composites as Anode Materials for Lithium Batteries [J]. Journal of Guangdong University of Technology, 2014, 31(2): 27-31.doi: 10.12052/gdutxb.230116
[4] LIANG Qi-Feng, KE Xiu-Fang, SHU Chang, LI Xiao-Ting, MA Bin-. Research on the Corrosion of TP317、HAL77-2 in Papermaking Recycled Water [J]. Journal of Guangdong University of Technology, 2014, 31(1): 131-135.doi: 10.12052/gdutxb.230116
[5] WANG Li-Jie. The Design of an Electrode Appliance for Alarm and Control of Failure of Sacrificiai Anode [J]. Journal of Guangdong University of Technology, 2010, 27(1): 64-66.doi: 10.12052/gdutxb.230116
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!