Journal of Guangdong University of Technology ›› 2023, Vol. 40 ›› Issue (06): 62-74.doi: 10.12052/gdutxb.230112

• Catalytic and Energy Materials • Previous Articles     Next Articles

Single-atom Catalysts for Lithium-sulfur Batteries

Chen Chao1, Lei Yuan1, Lin Zhan1,2, Zhang Shan-qing1,2   

  1. 1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;
    2. Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Jieyang 515200, China
  • Received:2023-08-23 Online:2023-11-25 Published:2023-11-08

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Abstract: Owing to advantages of high theoretical energy density, low cost and environmental friendliness, lithium-sulfur (Li-S) battery is considered as one of the most promising next-generation high-energy-density batteries. The "shuttle effect" of polysulfides is the key issue hindering the commercialization of Li-S batteries. Adoption of "catalytic" strategy to enhance the sulfur redox kinetics has been demonstrated to be an effective way to alleviate the "shuttle effect". Single-atom catalysts (SACs) have received much attention in the field of catalysis due to their uniform metal active centers, unique electronic properties, and theoretically 100% metal atom utilization. In recent years, SACs have been introduced into Li-S systems and studied to achieve fast sulfur conversion kinetics. In this research, the latest progress in the application of SACs in Li-S batteries was reviewed, with special emphasis on the discussion of key factors affecting the catalytic activity of SACs. The prospects of SACs for Li-S batteries were pointed out and highlighted. Important guidance is provided for future design and fabrication of high-performance SACs for Li-S battery application.

Key words: single-atom catalysts, lithium-sulfur battery, polysulfides, catalysis, redox kinetics

CLC Number: 

  • TQ152
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