广东工业大学学报 ›› 2023, Vol. 40 ›› Issue (06): 62-74.doi: 10.12052/gdutxb.230112

• 催化与能源材料 • 上一篇    下一篇

单原子催化剂在锂硫电池中的应用

陈超1, 雷源1, 林展1,2, 张山青1,2   

  1. 1. 广东工业大学 轻工化工学院, 广东 广州 510006;
    2. 化学与精细化工广东省实验室 揭阳分中心, 广东 揭阳 515200
  • 收稿日期:2023-08-23 出版日期:2023-11-25 发布日期:2023-11-08
  • 作者简介:陈超(1983-),男,副教授,工学博士,主要研究方向为纳米多孔材料的设计制备及其在能源和环境中的应用研究,E-mail:c.chen@gdut.edu.cn
  • 基金资助:
    国家自然科学基金资助面上项目 (52171204)

Single-atom Catalysts for Lithium-sulfur Batteries

Chen Chao1, Lei Yuan1, Lin Zhan1,2, Zhang Shan-qing1,2   

  1. 1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;
    2. Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Jieyang 515200, China
  • Received:2023-08-23 Online:2023-11-25 Published:2023-11-08

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摘要： 锂硫电池具有理论能量密度高、成本低、环境友好等优点，被认为是最有前景的下一代高能量密度电池之一。多硫化物的“穿梭效应”是阻碍锂硫电池商业化的关键问题。采用“催化”策略增强硫物种之间的氧化还原反应动力学已被证明是缓解“穿梭效应”的有效方法。单原子催化剂由于其均匀的金属活性中心、独特的电子特性和理论上100 %的金属原子利用效率，在催化领域得到了广泛关注。近年来，单原子催化剂被引入到锂硫电池体系中，以实现硫物种之间转化反应的快速动力学。本文以影响单原子催化剂活性的几个关键因素为主线，综述了单原子催化剂在锂硫电池领域应用的主要进展，并对锂硫电池用单原子催化剂的前景进行了展望。本文对未来设计制备高活性的锂硫电池用单原子催化剂提供了思路。

关键词: 单原子催化剂, 锂硫电池, 多硫化物, 催化, 氧化还原动力学

Abstract: Owing to advantages of high theoretical energy density, low cost and environmental friendliness, lithium-sulfur (Li-S) battery is considered as one of the most promising next-generation high-energy-density batteries. The "shuttle effect" of polysulfides is the key issue hindering the commercialization of Li-S batteries. Adoption of "catalytic" strategy to enhance the sulfur redox kinetics has been demonstrated to be an effective way to alleviate the "shuttle effect". Single-atom catalysts (SACs) have received much attention in the field of catalysis due to their uniform metal active centers, unique electronic properties, and theoretically 100% metal atom utilization. In recent years, SACs have been introduced into Li-S systems and studied to achieve fast sulfur conversion kinetics. In this research, the latest progress in the application of SACs in Li-S batteries was reviewed, with special emphasis on the discussion of key factors affecting the catalytic activity of SACs. The prospects of SACs for Li-S batteries were pointed out and highlighted. Important guidance is provided for future design and fabrication of high-performance SACs for Li-S battery application.

Key words: single-atom catalysts, lithium-sulfur battery, polysulfides, catalysis, redox kinetics

中图分类号: 

  • TQ152
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